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Date: | Wed, 28 Oct 2015 13:17:36 -0500 |
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From Wikipedia:
Lead content
To enhance the machinability of brass, lead is often added in
concentrations of around 2%. Since lead has a lower melting point than
the other constituents of the brass, it tends to migrate towards the
grain boundaries in the form of globules as it cools from casting. The
pattern the globules form on the surface of the brass increases the
available lead surface area which in turn affects the degree of
leaching. In addition, cutting operations can smear the lead globules
over the surface. These effects can lead to significant lead leaching
from brasses of comparatively low lead content.[9]
Silicon is an alternative to lead; however, when silicon is used in a
brass alloy, the scrap must never be mixed with leaded brass scrap
because of contamination and safety problems.[10]
In October 1999 the California State Attorney General sued 13 key
manufacturers and distributors over lead content. In laboratory tests,
state researchers found the average brass key, new or old, exceeded the
California Proposition 65 limits by an average factor of 19, assuming
handling twice a day.[11] In April 2001 manufacturers agreed to reduce
lead content to 1.5%, or face a requirement to warn consumers about lead
content. Keys plated with other metals are not affected by the
settlement, and may continue to use brass alloys with higher percentage
of lead content.[12][13]
Also in California, lead-free materials must be used for "each component
that comes into contact with the wetted surface of pipes and pipe
fittings, plumbing fittings and fixtures." On January 1, 2010, the
maximum amount of lead in "lead-free brass" in California was reduced
from 4% to 0.25% lead. The common practice of using pipes for electrical
grounding is discouraged, as it accelerates lead corrosion.[14][15]
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