Here are a few dates that may be of interest. Don't ask - no hard
references, just culled from years of reading.
Bakelite: invented by Leo Hendrick Baekeland in 1906. Pat. in either 1908
or 1909, and available in colors a few years later.
PVC: 1933.
Ballpoint pen: invented by Laszlo Biro in 1938.
Teflon: invented 1938. Pat. by DuPont and made available in 1948.
Roberta Greenwood